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The air particles within the sealed syringe expand because the heat from the water gives it energy. And when energy is added to a substance, the particles have more energy to break away from the attractions set on by the other particles. In other words, it expands. (hope that answers it for you.)

as the air particles gain heat energy ,they convert this energy into their kinectic energy which makes the particles of the air to move more faster and apart from each other hence resulting in expansion

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