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The first to observe (but not explain) the photoelectric effect were Hertz and Hallwachs in 1887.

Albert Einstein received the 1921 Nobel Prize for physics:

...for his services to Theoretical Physics, and especially for his discovery of the law of the photoelectric effect.

His 1905 paper explaining the photoelectric effect was rejected by physicists of that time and only accepted after experiments by Robert Andrews Millikan in 1914 showed that predictions made by Einstein's theory were correct - such as that the energy of individual ejected electrons increases linearly with the frequency of the light.

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