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Metahne does not have a higher boiling point than methane. Fluoromethane, CH3F, has a boiling point of 195K, -78.2C, methane, CH4, has a boiling point of 109K approx -164 C. I make that fluoromethane has a higher temeprature boiling point than methane. This is what you would expect, London dispersion forces will be greater in CH3F as it has more electrons than CH4. CH3F is polar and there will be dipole dipole interactions which will not be present in CH4.

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