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A process will be spontaneous when the change in Gibbs free energy is negative.
The change in Gibbs free energy can be calculated from the equation:
G2 - G1 = H2 - H1 - T(S2 - S1)
where
G is Gibbs free energy
H is Enthalpy
T is absolute temperature (when T is given in Kelvin or Rankine it is an absolute temperature)
S is Entropy
In this case
H2 - H1 = 125 kJ
T = 293 K
S2 - S1 = 35 J/K = 0.035 kJ/K
so doing the math you get
G2 - G1 = 125 - 293(0.35) = 22.45 > 0 so the process is not spontaneous in the direction where enthalpy change and entropy change are being measured. The reverse process would be spontaneous.
What else can I help you with?
How does gibbs energy relate to the changes in ethalpy and ethropy?
Gibbs energy accounts for both enthalpy (heat) and entropy (disorder) in a system. A reaction will be spontaneous if the Gibbs energy change is negative, which occurs when enthalpy is negative (exothermic) and/or entropy is positive (increased disorder). The relationship between Gibbs energy, enthalpy, and entropy is described by the equation ΔG = ΔH - TΔS, where T is temperature in Kelvin.
What is the difference between the Gibbs and Helmholtz free energy equations and how do they relate to each other in thermodynamics?
The Gibbs free energy equation considers both the enthalpy and entropy of a system, while the Helmholtz free energy equation only considers the internal energy and entropy. In thermodynamics, these equations are related through the relationship G H - TS, where G is the change in Gibbs free energy, H is the change in enthalpy, S is the change in entropy, and T is the temperature. This equation helps determine whether a reaction is spontaneous or non-spontaneous at a given temperature.
What does Gibbs free energy depends on?
it depends on the entropy and enathalpy of the reaction
What is the relationship between entropy and free energy in thermodynamics?
In thermodynamics, entropy and free energy are related through the equation G H - TS, where G is the change in free energy, H is the change in enthalpy, T is the temperature in Kelvin, and S is the change in entropy. This equation shows that the change in free energy is influenced by both the change in enthalpy and the change in entropy.
What is true about the numerical value of the Gibbs free-energy change for a spontaneous reaction?
For a spontaneous reaction, the numerical value of the Gibbs free-energy change (ΔG) is negative, indicating that the reaction is energetically favorable and will proceed in the forward direction. This negative ΔG means that the system is releasing energy and increasing in entropy during the reaction.
Which statement describes a reaction at 298 K if H 31 kJ mol S 0.093 kJ molK?
It is not spontaneous.
What could make G become negative at a given enthalpy and entropy?
Changing the temperature
What is the relationship between enthalpy, entropy, and free energy in a chemical reaction?
In a chemical reaction, enthalpy, entropy, and free energy are related. Enthalpy is the heat energy exchanged during a reaction, entropy is the measure of disorder or randomness, and free energy is the energy available to do work. The relationship between these three factors is described by the Gibbs free energy equation: G H - TS, where G is the change in free energy, H is the change in enthalpy, S is the change in entropy, and T is the temperature in Kelvin. This equation shows that for a reaction to be spontaneous, the change in free energy must be negative, meaning that the enthalpy change and entropy change must work together in the right direction.
What is the relationship between the enthalpy h and entropy s of a reaction that is spontaneous at higher temperatures but not at lower temperatures?
The relationship between enthalpy (H) and entropy (S) is described by the Gibbs free energy equation, ΔG = ΔH - TΔS, where ΔG is the change in Gibbs free energy, ΔH is the change in enthalpy, T is the temperature in Kelvin, and ΔS is the change in entropy. For a reaction to be spontaneous at higher temperatures but not at lower temperatures, the entropy term (TΔS) must dominate over the enthalpy term (ΔH) in the Gibbs free energy equation. This suggests that the increase in entropy with temperature plays a more significant role in driving the reaction towards spontaneity than the enthalpy change.
What conditions will a low temperature male a reaction spontaneous?
A reaction will be spontaneous at low temperatures if the decrease in enthalpy (change in heat content) of the reaction is greater than the decrease in entropy (measure of disorder) multiplied by the temperature. This can be represented by the equation ΔG = ΔH - TΔS, where ΔG is the change in Gibbs free energy, ΔH is the change in enthalpy, T is the temperature in Kelvin, and ΔS is the change in entropy.
Is the change in entropy, delta S, positive or negative for a spontaneous reaction?
For a spontaneous reaction, the change in entropy (delta S) is typically positive.
How does the Gibbs free energy predict spontaneity?
It tells if the reaction will process spontaneously or not
What kind of enthalpy change favors a spontaneous reaction?
For a spontaneous reaction, the overall change in enthalpy should be negative (exothermic). This means that the products have a lower enthalpy than the reactants, releasing energy in the form of heat.
How form a spontaneous reaction 298 k?
A reaction will be spontaneous at 298 K if the Gibbs free energy change (ΔG) for the reaction is negative. This means that the reaction will proceed in the forward direction without requiring an external input of energy. The equation ΔG = ΔH - TΔS can be used to determine if a reaction is spontaneous at a given temperature, where ΔH is the change in enthalpy and ΔS is the change in entropy.
Do chemical reactions that increase entropy tend to occur spontaneously?
Reactions that increase the randomness. Reactions that have more moles of gas on the product side than the reactant side increase entropy. Also reactions that have a positive change in spontaneity and a negative enthalpy.
How does gibbs energy relate to the changes in ethalpy and ethropy?
Gibbs energy accounts for both enthalpy (heat) and entropy (disorder) in a system. A reaction will be spontaneous if the Gibbs energy change is negative, which occurs when enthalpy is negative (exothermic) and/or entropy is positive (increased disorder). The relationship between Gibbs energy, enthalpy, and entropy is described by the equation ΔG = ΔH - TΔS, where T is temperature in Kelvin.
How do you determine whether a reaction is spontaneous or non spontaneous?
The first of two factors that determine whether a reaction is spontaneous or non-spontaneous is entropy. The second is energy. For a reaction to be spontaneous, it must have both of these factors.
