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Two US states have no land borders with other states : Alaska and Hawaii. The state with just one bordering state is Maine (borders New Hampshire).
virgina
Two slave states were indsputably Union states: Delaware and Maryland. Three slave states had two state governments, a Unionist one and a Confederate one, both claiming to be the legitimate government of their state: Kentucky, Missouri, Virginia.
Mississippi
Hawaii was in 1960 (50th state), Alaska 1958 (49th state).