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osmosis

  (ŏz-mō'sĭs, ŏs-) pronunciation
n., pl. -ses (-sēz).
    1. Diffusion of fluid through a semipermeable membrane from a solution with a low solute concentration to a solution with a higher solute concentration until there is an equal concentration of fluid on both sides of the membrane.
    2. The tendency of fluids to diffuse in such a manner.
  1. A gradual, often unconscious process of assimilation or absorption: learned French by osmosis while residing in Paris for 15 years.

[From obsolete osmose, from earlier endosmose, from French : Greek endo-, endo- + Greek ōsmos, thrust, push (from ōthein, to push).]

osmotic os·mot'ic (-mŏt'ĭk) adj.
osmotically os·mot'i·cal·ly adv.
 
 

Concept

The term osmosis describes the movement of a solvent through a semipermeable membrane from a less concentrated solution to a more concentrated one. Water is sometimes called "the perfect solvent," and living tissue (for example, a human being's cell walls) is the best example of a semipermeable membrane. Osmosis has a number of life-preserving functions: it assists plants in receiving water, it helps in the preservation of fruit and meat, and is even used in kidney dialysis. In addition, osmosis can be reversed to remove salt and other impurities from water.

How It Works

If you were to insert a hollow tube of a certain diameter into a beaker of water, the water would rise inside the tube and reach the same level as the water outside it. But suppose you sealed the bottom end of the tube with a semipermeable membrane, then half-filled the tube with salt water and again inserted it into the beaker. Over a period of time, the relative levels of the salt water in the tube and the regular water in the beaker would change, with the fresh water gradually rising into the beaker.

This is osmosis at work; however, before investigating the process, it is necessary to understand at least three terms. A solvent is a liquid capable of dissolving or dispersing one or more other substances. A solute is the substance that is dissolved, and a solution is the resulting mixture of solvent and solute. Hence, when you mix a packet of sugar into a cup of hot coffee, the coffee—which is mostly water—acts as a solvent for the sugar, a solute, and the resulting sweetened coffee is a solution. (Indeed, people who need a cup of coffee in the morning might say that it is a "solution" in more ways than one!) The relative amount of solute in the solution determines whether it can be described as more or less concentrated.

Water and Oil: Molecular Differences

In the illustrations involving the beaker and the hollow tube, water plays one of its leading roles, as a solvent. It is possible to use a number of other solvents for osmosis, but most of the ones that will be discussed here are water-based substances. In fact, virtually everything people drink is either made with water as its central component (soft drinks, coffee, tea, beer and spirits), or comes from a water-based plant or animal life form (fruit juices, wine, milk.) Then of course there is water itself, still the world's most popular drink.

By contrast, people are likely to drink an oily product only in extreme circumstances: for instance, to relieve constipation, holistic-health practitioners often recommend a mixture of olive oil and other compounds for this purpose. Oil, unlike water, has a tendency to pass straight through a person's system, without large amounts of it being absorbed through osmosis. In fact, oil and water differ significantly at the molecular level.

Water is the best example of a polar molecule, sometimes called a dipole. As everyone knows, water is a name for the chemical H2O, in which two relatively small hydrogen atoms bond with a large atom of oxygen. You can visualize a water molecule by imagining oxygen as a basketball with hydrogen as two baseballs fused to the basketball's surface. Bonded together as they are, the oxygen tends to pull electrons from the hydrogen atoms, giving it a slight negative charge and the hydrogen a slight positive charge.

As a result, one end of a water molecule has a positive electrical charge, and the other end a negative charge. This in turn causes the positive end of one molecule to attract the negative side of its neighbor, and vice versa. Though the electromagnetic force is weak, even in relative terms, it is enough to bond water molecules tightly to one another.

By contrast, oily substances—whether the oil is animal-, vegetable-, or petroleum-based—are typically nonpolar, meaning that the positive and negative charges are distributed evenly across the surface of the molecule. Hence, the bond between oil molecules is much less tight than for water molecules. Clean motor oil in a car's crankshaft behaves as though it were made of millions of tiny ball-bearings, each rolling through the engine without sticking. Water, on the other hand, has a tendency to stick to surfaces, since its molecules are so tightly bonded to one another.

This tight bond gives water highly unusual properties compared to other substances close to its molecular weight. Among these are its high boiling point, its surprisingly low density when frozen, and the characteristics that make osmosis possible. Thanks to its intermolecular structure, water is not only an ideal solvent, but its closely packed structure enables easy movement, as, for instance, from an area of low concentration to an area of high concentration.

In the beaker illustration, the "pure" water is almost pure solvent. (Actually, because of its solvent qualities, water seldom appears in a pure state unless one distills it: even water flowing through a "pure" mountain stream carries all sorts of impurities, including microscopic particles of the rocks over which it flows.) In any case, the fact that the water in the beaker is almost pure makes it easy for it to flow through the semipermeable membrane in the bottom of the tube. By contrast, the solute particles in the salt-water solution have a much harder time passing through, and are much more likely to block the openings in the membrane. As a result, the movement is all in one direction: water in the beaker moves through the membrane, and into the tube.

A few points of clarification are in order here. A semipermeable membrane is anything with a structure somewhere between that of, say, plastic on the one hand and cotton on the other. Were the tube in the beaker covered with Saran wrap, for instance, no water would pass through. On the other hand, if one used a piece of cotton in the bottom of the tube, the water would pass straight through without osmosis taking place. In contrast to cotton, Gore-tex is a fabric containing a very thin layer of plastic with billions of tiny pores which let water vapor flow out without allowing liquid water to seep in. This accounts for the popularity of Gore-tex for outdoor gear—it keeps a person dry without holding in their sweat. So Gore-tex would work well as a semipermeable membrane.

Also, it is important to consider the possibilities of what can happen during the process of osmosis. If the tube were filled with pure salt, or salt with only a little water in it, osmosis would reach a point and then stop due to osmotic pressure within the substance. Osmotic pressure results when a relatively concentrated substance takes in a solvent, thus increasing its pressure until it reaches a point at which the solution will not allow any more solvent to enter.

Real-Life Applications

Cell Behavior and Salt Water

Cells in the human body and in the bodies of all living things behave like microscopic bags of solution housed in a semipermeable membrane. The health and indeed the very survival of a person, animal, or plant depends on the ability of the cells to maintain their concentration of solutes.

Two illustrations involving salt water demonstrate how osmosis can produce disastrous effects in living things. If you put a carrot in salty water, the salt water will "draw" the water from inside the carrot—which, like the human body and most other forms of life, is mostly made up of water. Within a few hours, the carrot will be limp, its cells shriveled.

Worse still is the process that occurs when a person drinks salt water. The body can handle a little bit, but if you were to consume nothing but salt water for a period of a few days, as in the case of being stranded on the proverbial desert island, the osmotic pressure would begin drawing water from other parts of your body. Since a human body ranges from 60% water (in an adult male) to 85% in a baby, there would be a great deal of water available—but just as clearly, water is the essential ingredient in the human body. If you continued to ingest salt water, you would eventually experience dehydration and die.

How, then, do fish and other forms of marine life survive in a salt-water environment? In most cases, a creature whose natural habitat is the ocean has a much higher solute concentration in its cells than does a land animal. Hence, for them, salt water is an isotonic solution, or one that has the same concentration of solute—and hence the same osmotic pressure—as in their own cells.

Osmosis in Plants

Plants depend on osmosis to move water from their roots to their leaves. The further toward the edge or the top of the plant, the greater the solute concentration, which creates a difference in osmotic pressure. This is known as osmotic potential, which draws water upward. In addition, osmosis protects leaves against losing water through evaporation.

Crucial to the operation of osmosis in plants are "guard cells," specialized cells dispersed along the surface of the leaves. Each pair of guard cells surrounds a stoma, or pore, controlling its ability to open and thus release moisture.

In some situations, external stimuli such as sunlight may cause the guard cells to draw in potassium from other cells. This leads to an increase in osmotic potential: the guard cell becomes like a person who has eaten a dry biscuit, and is now desperate for a drink of water to wash it down. As a result of its increased osmotic potential, the guard cell eventually takes on water through osmosis. The guard cells then swell with water, opening the stomata and increasing the rate of gas exchange through them. The outcome of this action is an increase in the rate of photosynthesis and plant growth.

When there is a water shortage, however, other cells transmit signals to the guard cells that cause them to release their potassium. This decreases their osmotic potential, and water passes out of the guard cells to the thirsty cells around them. At the same time, the resultant shrinkage in the guard cells closes the stomata, decreasing the rate at which water transpires through them and preventing the plant from wilting.

Osmosis and Medicine

Osmosis has several implications where medical care is concerned, particularly in the case of the storage of vitally important red blood cells. These are normally kept in a plasma solution which is isotonic to the cells when it contains specific proportions of salts and proteins. However, if red blood cells are placed in a hypotonic solution, or one with a lower solute concentration than in the cells themselves, this can be highly detrimental.

Hence water, a life-giving and life-preserving substance in most cases, is a killer in this context. If red blood cells were stored in pure water, osmosis would draw the water into the cells, causing them to swell and eventually burst. Similarly, if the cells were placed in a solution with a higher solute concentration, or hypertonic solution, osmosis would draw water out of the cells until they shriveled.

In fact, the plasma solution used by most hospitals for storing red blood cells is slightly hypertonic relative to the cells, to prevent them from drawing in water and bursting. Physicians use a similar solution when injecting a drug intravenously into a patient. The active ingredient of the drug has to be suspended in some kind of medium, but water would be detrimental for the reasons discussed above, so instead the doctor uses a saline solution that is slightly hypertonic to the patient's red blood cells.

One vital process closely linked to osmosis is dialysis, which is critical to the survival of many victims of kidney diseases. Dialysis is the process by which an artificial kidney machine removes waste products from a patients' blood—performing the role of a healthy, normally functioning kidney. The openings in the dialyzing membrane are such that not only water, but salts and other waste dissolved in the blood, pass through to a surrounding tank of distilled water. The red blood cells, on the other hand, are too large to enter the dialyzing membrane, so they return to the patient's body.

Preserving Fruits and Meats

Osmosis is also used for preserving fruits and meats, though the process is quite different for the two. In the case of fruit, osmosis is used to dehydrate it, whereas in the preservation of meat, osmosis draws salt into it, thus preventing the intrusion of bacteria.

Most fruits are about 75% water, and this makes them highly susceptible to spoilage. To preserve fruit, it must be dehydrated, which—as in the case of the salt in the meat—presents bacteria with a less-than-hospitable environment. Over the years, people have tried a variety of methods for drying fruit, but most of these have a tendency to shrink and harden the fruit. The reason for this is that most drying methods, such as heat from the Sun, are relatively quick and drastic; osmosis, on the other hand, is slower, more moderate—and closer to the behavior of nature.

Osmotic dehydration techniques, in fact, result in fruit that can be stored longer than fruit dehydrated by other methods. This in turn makes it possible to provide consumers with a wider variety of fruit throughout the year. Also, the fruit itself tends to maintain more of its flavor and nutritional qualities while keeping out microorganisms.

Because osmosis alone can only remove about 50% of the water in most ripe fruits, however, the dehydration process involves a secondary method as well. First the fruit is blanched, or placed briefly in scalding water to stop enzymatic action. Next it is subjected to osmotic dehydration by dipping it in, or spreading it with, a specially made variety of syrup whose sugar draws out the water in the fruit. After this, air drying or vacuum drying completes the process. The resulting product is ready to eat; can be preserved on a shelf under most climatic conditions; and may even be powdered for making confectionery items.

Whereas osmotic dehydration of fruit is currently used in many parts of the world, the salt-curing of meat in brine is largely a thing of the past, due to the introduction of refrigeration. Many poorer families, even in the industrialized world, however, remained without electricity long after it spread throughout most of Europe and North America. John Steinbeck's Grapes of Wrath (1939) offers a memorable scene in which a contemporary family, the Joads, kill and cure a pig before leaving Oklahoma for California. And a Web site for Walton Feed, an Idaho company specializing in dehydrated foods, offers reminiscences by Canadians whose families were still salt-curing meats in the middle of the twentieth century. Verla Cress of southern Alberta, for instance, offered a recipe from which the following details are drawn.

First a barrel is filled with a solution containing 2 gal (7.57 l) of hot water and 8 oz (.2268 kg) of salt, or 32 parts hot water to one part salt, as well as a small quantity of vinegar. The pig or cow, which would have just been slaughtered, should then be cut up into what Cress called "ham-sized pieces (about 10-15 lb [5-7 kg]) each." The pieces are then soaked in the brine barrel for six days, after which the meat is removed, dried, "and put… in flour or gunny sacks to keep the flies away. Then hang it up in a cool dry place to dry. It will keep like this for perhaps six weeks if stored in a cool place during the Summer. Of course, it will keep much longer in the Winter. If it goes bad, you'll know it!"

Cress offered another method, one still used on ham today. Instead of salt, sugar is used in a mixture of 32 oz (.94 l) to 3 gal (11.36 l) of water. After being removed, the meat is smoked—that is, exposed to smoke from a typically aromatic wood such as hickory, in an enclosed barn—for three days. Smoking the meat tends to make it last much longer: four months in the summer, according to Cress.

The Walton Feeds Web page included another brine-curing recipe, this one used by the women of the Stirling, Alberta, Church of the Latter-Day Saints in 1973. Also included were reminiscences by Glenn Adamson (born 1915): "…When we butchered a pig, Dad filled a wooden 45-gal (170.34 l) barrel with salt brine. We cut up the pig into maybe eight pieces and put it in the brine barrel. The pork soaked in the barrel for several days, then the meat was taken out, and the water was thrown away…. In the hot summer days after they [the pieces of meat] had dried, they were put in the root cellar to keep them cool. The meat was good for eating two or three months this way."

For thousands of years, people used salt to cure and preserve meat: for instance, the sailing ships that first came to the New World carried on board barrels full of cured meat, which fed sailors on the voyage over. Meat was not the only type of food preserved through the use of salt or brine, which is hypertonic—and thus lethal—to bacteria cells. Among other items packed in brine were fish, olives, and vegetables.

Even today, some types of canned fish come to the consumer still packed in brine, as do olives. Another method that survives is the use of sugar—which can be just as effective as salt for keeping out bacteria—to preserve fruit in jam.

Reverse Osmosis

Given the many ways osmosis is used for preserving food, not to mention its many interactions with water, it should not be surprising to discover that osmosis can also be used for desalination, or turning salt water into drinking water. Actually, it is not osmosis, strictly speaking, but rather reverse osmosis that turns salt water from the ocean—97% of Earth's water supply—into water that can be used for bathing, agriculture, and in some cases even drinking.

When you mix a teaspoon of sugar into a cup of coffee, as mentioned in an earlier illustration, this is a non-reversible process. Short of some highly complicated undertaking—for instance, using ultrasonic sound waves—it would be impossible to separate solute and solvent.

Osmosis, on the other hand, can be reversed. This is done by using a controlled external pressure of approximately 60 atmospheres, an atmosphere being equal to the air pressure at sea level—14.7 pounds-per-square-inch (1.013 × 105 Pa.) In reverse osmosis, this pressure is applied to the area of higher solute concentration—in this case, the seawater. As a result, the pressure in the seawater pushes water molecules into a reservoir of pure water.

If performed by someone with a few rudimentary tools and a knowledge of how to provide just the right amount of pressure, it is possible that reverse osmosis could save the life of a shipwreck victim stranded in a location without a fresh water supply. On the other hand, a person in such a situation may be able to absorb sufficient water from fruits and plant life, as Tom Hanks's character did in the 2001 film Cast Away.

Companies such as Reverse Osmosis Systems in Atlanta, Georgia, offer a small unit for home or business use, which actually performs the reverse-osmosis process on a small scale. The unit makes use of a process called crossflow, which continually cleans the semipermeable membrane of impurities that have been removed from the water. A small pump provides the pressure necessary to push the water through the membrane. In addition to an under-the-sink model, a reverse osmosis water cooler is also available.

Not only is reverse osmosis used for making water safe, it is also applied to metals in a variety of capacities, not least of which is its use in treating wastewater from electroplating. But there are other metallurgical methods of reverse osmosis that have little to do with water treatment: metal finishing, as well as recycling of metals and chemicals. These processes are highly complicated, but they involve the same principle of removing impurities that governs reverse osmosis.

Where to Learn More

Francis, Frederick J., editor-in-chief. Encyclopedia of FoodScience and Technology. New York: Wiley, 2000.

Gardner, Robert. Science Project Ideas About KitchenChemistry. Berkeley, N.J.: Enslow Publishers, 2002.

Laschish, Uri. "Osmosis, Reverse Osmosis, and OsmoticPressure: What They Are" (Web site). <http://members.tripod.com/~urila/> (February 20, 2001).

"Lesson 5: Osmosis" (Web site). <http://www.biologylessons.sdsu.edu/classes/lab5/semnet/> (February 20, 2001).

Rosenfeld, Sam. Science Experiments with Water. Illustrated by John J. Floherty, Jr. Irvington-on-Hudson, NY: Harvey House, 1965.

"Salt-Curing Meat in Brine." Walton Feed (Web site). <http://waltonfeed.com/old/brine.html> (February 20, 2001).


 

The transport of solvent through a semipermeable membrane separating two solutions of different solute concentration. The solvent diffuses from the solution that is dilute in solute to the solution that is concentrated.

The flow of liquid through such a barrier may be stopped by applying pressure to the liquid on the side of higher solute concentration. The applied pressure required to prevent the flow of solvent across a perfectly semipermeable membrane is called the osmotic pressure and is a characteristic of the solution. The walls of cells in living organisms permit the passage of water and certain solutes, while preventing the passage of other solutes, usually of relatively high molecular weight. These walls act as selectively permeable membranes, and allow osmosis to occur between the interior of the cell and the surrounding media. See also Solution.


 

A term describing the movement of fluid (usually water) across a semipermeable membrane. The membrane is described as semipermeable because it allows water, but not dissolved substances, to cross it. Water moves across the membrane from where the concentration of dissolved substances is lowest to where it is highest. Thus, water moves down its concentration gradient from high concentration to low concentration. The process continues until the concentration of solutes is the same on both sides of the membrane. The nature of the dissolved substances is unimportant, other than their not being able to penetrate the membrane. The membranes of most living cells are semipermeable, and cells swell if they are placed in a solution containing less dissolved substance than blood (hypotonic), and shrink in more concentrated (hypertonic) solutions. Hydrostatic pressure can be applied to oppose fluid movement; the pressure required to oppose the movement exactly is the ‘osmotic pressure’. Thus cells can act as osmometers, by changing shape when the tonicity of the bathing solution changes. In the hypothalamus are cells which are very sensitive to osmotic changes in the blood. If, for example, blood becomes hypertonic, as in thirst, the cells respond by sending impulses to the posterior pituitary to release antidiuretic hormone, which prevents further fluid loss by the kidneys. Alternatively, if large amounts of fluid (beer, for example) are imbibed, antidiuretic hormone is cut off and diuresis ensues.

— Alan W. Cuthbert

See also body fluids; cell.

 

The passage of water through a semi-permeable membrane, from a region of low concentration of solutes to one of higher concentration. Reverse osmosis is the passage of water from a more concentrated to a less concentrated solution through a semi-permeable membrane by the application of pressure. Used for desalination of sea water, concentration of fruit juices, and processing of whey. The membranes commonly used are cellulose acetate or polyamide of very small pore size, 10-4-10-3 μm. See also osmotic pressure.

 

n

The passage of pure solvent from the lesser to the greater concentration when two solutions are separated by a membrane that selectively prevents the passage of solute molecules but is permeable to the solvent. The principles of osmosis and the selective permeability of the cell membrane help to regulate the transfer of fluids and metabolites to and from the cells. Thus, they also maintain the stability of the salt/ion concentration in the extracellular and intracellular fluids.

 

The passage of a weaker solution to a stronger solution through a semi-permeable membrane. In soils, the more dilute soil moisture passes by osmotic pressure into plant roots. In this way, soil moisture is taken up by plants.

 

Spontaneous passage or diffusion of water or other solvent through a semipermeable membrane. If a solution is separated from a pure solvent by a membrane that is permeable to the solvent but not to the solute, the solution will tend to become more dilute by absorbing solvent through the membrane. The pressure caused by the migration of solvent through the membrane is called osmotic pressure.

For more information on osmosis, visit Britannica.com.

 

The net movement of water (or another solvent) from a high water potential (or low solute concentration) to a low water potential (or high solute concentration) through a semi-permeable membrane (i.e. a membrane through which only solvent passes).

 
(ŏzmō'sĭs) , transfer of a liquid solvent through a semipermeable membrane that does not allow dissolved solids (solutes) to pass. Osmosis refers only to transfer of solvent; transfer of solute is called dialysis. In either case the direction of transfer is from the area of higher concentration of the material transferred to the area of lower concentration. This spontaneous migration of a material from a region of higher concentration to a region of lower concentration is called diffusion.

Principles of Osmosis

Osmosis will occur if a vessel is separated into two compartments by a semipermeable membrane, both compartments are filled to the same level with a solvent, and solute is added to one side. The level of the liquid on the side containing the solute will rise as the solvent flows from the side of its higher concentration to the side of lower concentration. If an external pressure is exerted on the side containing the solute, the transfer of solvent can be stopped and even reversed (reverse osmosis). Two solutions separated by a semipermeable membrane are said to be isotonic if no osmosis occurs. If osmosis occurs, transfer of solvent is from the hypotonic solution to the hypertonic solution, which has the higher osmotic pressure.

The minimum pressure necessary to stop solvent transfer is called the osmotic pressure. Since the osmotic pressure is related to the concentration of solute particles, there is a mathematical relationship between osmotic pressure, freezing-point depression, and boiling-point elevation. Properties such as osmotic pressure, freezing point, and boiling point, which depend on the number of particles present rather than on their size or chemical nature, are called colligative properties. For dilute solutions the mathematical relationship between the osmotic pressure, temperature, and concentration of solute is much like the relation between pressure, temperature, and volume in an ideal gas (see gas laws). A number of theories explaining osmotic pressure by analogy to gases have been devised, but most have been discarded in favor of thermodynamic interpretations using such concepts as the entropy of dilution.

Biological Importance of Osmosis

Osmosis and dialysis are of prime importance in living organisms, where they influence the distribution of nutrients and the release of metabolic waste products. Living cells of both plants and animals are enclosed by a semipermeable membrane called the cell membrane, which regulates the flow of liquids and of dissolved solids and gases into and out of the cell. The membrane forms a selective barrier between the cell and its environment; not all substances can pass through the membrane with equal facility. Without this selectivity, the substances necessary to the life of the cell would diffuse uniformly into the cell's surroundings, and toxic materials from the surroundings would enter the cell.

If blood cells (or other cells) are placed in contact with an isotonic solution, they will neither shrink nor swell. If the solution is hypertonic, the cells will lose water and shrink (plasmolyze). If the solution is hypotonic (or if pure solvent is used) the cells will swell; the osmotic pressure that is developed may even be great enough to rupture the cell membrane. Saltwater from the ocean is hypertonic to the cells of the human body; the drinking of ocean water dehydrates body tissues instead of quenching thirst.

In plants osmosis is at least partially responsible for the absorption of soil water by root hairs and for the elevation of the liquid to the leaves of the plant. However, plants wilt when watered with saltwater or treated with too much fertilizer, since the soil around their roots then becomes hypertonic.


 
(ahz-moh-sis, ahs-moh-sis)

The seeping of a fluid through a seemingly solid barrier, such as a cell wall or a rubber sheet. When the concentration of the fluid is the same on both sides of the barrier, osmosis stops.

  • Informally, “osmosis” is the process by which information or concepts come to a person without conscious effort: “Living in Paris, he learned French slang by osmosis.”
  •  

    [Gr.] the passage of pure solvent from a solution of lesser to one of greater solute concentration when the two solutions are separated by a membrane which selectively prevents the passage of solute molecules, but is permeable to the solvent.
    The process of osmosis and the factors that influence it are important clinically in the maintenance of adequate body fluids and in the proper balance between volumes of extracellular and intracellular fluids.
    The term osmotic pressure refers to the amount of pressure necessary to stop the flow of water across the membrane. The hydrostatic pressure of the water exerts an opposite effect; that is, it exerts pressure in favor of the flow of water across the membrane. The osmotic pressure of the particles in a solute depends on the relative concentrations of the solutions on either side of the membrane, and on the area of the membrane. The osmotic pressure exerted by the nondiffusible particles in a solution is determined by the numbers of particles in a unit of fluid and not by the mass of the particles.

    Osmosis. By permission from Guyton R, Hall JE, Textbook of Medical Physiology, Saunders, 2000
     
    Wikipedia: osmosis

    Osmosis is the net movement of water across a partially permeable membrane from a region of high solvent potential to an area of low solvent potential, up a solute concentration gradient.It is a physical process in which a solvent moves, without input of energy, across a semi permeable membrane (permeable to the solvent, but not the solute) separating two solutions of different concentrations.[1] Osmosis releases energy, and can be made to do work, as when a growing tree-root splits a stone.

    Computer simulation of the process of osmosis
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    Computer simulation of the process of osmosis

    Net movement of solvent is from the less-concentrated (hypotonic) to the more-concentrated (hypertonic) solution, which tends to reduce the difference in concentrations. This effect can be countered by increasing the pressure of the hypertonic solution, with respect to the hypotonic. The osmotic pressure is defined to be the pressure required to maintain an equilibrium, with no net movement of solvent. Osmotic pressure is a colligative property, meaning that the property depends on the molar concentration of the solute but not on its identity. Osmosis is the result of diffusion across a semi-permeable membrane.

    Osmosis is important in biological systems as many biological membranes are semipermeable. In general, these membranes are impermeable to organic solutes with large molecules, such as polysaccharides, while permeable to water and small, uncharged solutes. Permeability may depend on solubility properties, charge, or chemistry as well as solute size. Water molecules travel through the plasma cell membrane, tonoplast (vacuole) or protoplast in two ways. Either by diffusing across the phospholipid bilayer directly, or via aquaporins (small transmembrane proteins similar to those in facilitated diffusion and in creating ion channels). Osmosis provides the primary means by which water is transported into and out of cells. The turgor pressure of a cell is largely maintained by osmosis, across the cell membrane, between the cell interior and its relatively hypotonic environment.

    Basic explanation

    Consider a permeable membrane, such as visking tubing, with apertures big enough to allow water (solvent) molecules, but not larger solute molecules, to pass through. When this membrane is immersed in liquid it is constantly hit by molecules of the liquid, in motion due to their thermal kinetic energy. In this respect solute and solvent molecules are indistinguishable. At a molecular scale, every time a molecule hits the membrane it has a defined likelihood of passing through. Here, there is a difference: for water molecules this probability is non-zero; for solute molecules it is zero.

    Suppose the membrane is in a volume of pure water. In this case, since the circumstances on both sides of the membrane are equivalent, water molecules pass in each direction at the same rate; there is no net flow of water through the membrane.

    If there is a solution on one side, and pure water on the other, the membrane is still hit by molecules from both sides at the same rate. However, some of the molecules hitting the membrane from the solution side will be solute molecules, and these will not pass through the membrane. So water molecules pass through the membrane from this side at a slower rate. This will result in a net flow of water to the side with the solution. Assuming the membrane does not break, this net flow will slow and finally stop as the pressure on the solution side becomes such that the movement in each direction is equal: dynamic equilibrium. This could either be due to the water potential on both sides of the membrane being the same, or due to osmosis being inhibited by factors such as pressure potential or Osmotic pressure.

    Osmosis can also be explained via the notion of entropy, from statistical mechanics. As above, suppose a permeable membrane separates equal amounts of pure solvent and a solution. Since a solution possesses more entropy than pure solvent, the second law of thermodynamics states that solvent molecules will flow into the solution until the entropy of the combined system is maximized. Notice that, as this happens, the solvent loses entropy while the solution gains entropy. Equilibrium, hence maximum entropy, is achieved when the entropy gradient becomes zero.

    Examples of osmosis

    Effect of different solutions on blood cells
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    Effect of different solutions on blood cells
    Plant cell under different enviroments
    Enlarge
    Plant cell under different enviroments

    Osmotic pressure is the main cause of support in many plants. The osmotic entry of water raises the turgor pressure exerted against the cell wall, until it equals the osmotic pressure, creating a steady state.

    When a plant cell is placed in a hypertonic solution, the water in the cells moves to an area higher in solute concentration, and the cell shrinks and so becomes flaccid. (This means the cell has become plasmolysed - the cell membrane has completely left the cell wall due to lack of water pressure on it; the opposite of turgid.)

    Also, osmosis is responsible for the ability of plant roots to suck up water from the soil. Since there are many fine roots, they have a large surface area, water enters the roots by osmosis.

    Osmosis can also be seen very effectively when potato slices are added to a high concentration of salt solution. The water from inside the potato moves to the salt solution, causing the potato to shrink and to lose its 'turgor pressure'. The more concentrated the salt solution, the bigger the difference in size and weight of the potato slice.

    In unusual environments, osmosis can be very harmful to organisms. For example, freshwater and saltwater aquarium fish placed in water of a different salinity than that they are adapted to will die quickly, and in the case of saltwater fish, rather dramatically. Another example of a harmful osmotic effect is the use of table salt to kill leeches and slugs.

    Suppose we place an animal or a plant cell in a solution of sugar or salt in water.

    1. If the medium is hypotonic — a dilute solution, with a higher water concentration than the cell — the cell will gain water through osmosis.
    2. If the medium is isotonic — a solution with exactly the same water concentration as the cell — there will be no net movement of water across the cell membrane.
    3. If the medium is hypertonic — a concentrated solution, with a lower water concentration than the cell — the cell will lose water by osmosis.[2]

    Chemical gardens demonstrate the effect of osmosis in inorganic chemistry.

    Osmotic pressure

    As mentioned before, osmosis may be opposed by increasing the pressure in the region of high solute concentration with respect to that in the low solute concentration region. The force per unit area, or pressure, required to prevent the passage of water through a selectively-permeable membrane and into a solution of greater concentration is equivalent to the osmotic pressure of the solution, or turgor. Osmotic pressure is a colligative property, meaning that the property depends on the concentration of the solute but not on its identity.

    Increasing the pressure increases the chemical potential of the system in proportion to the molar volume (δμ = δPV). Therefore, osmosis stops when the increase in potential due to pressure equals the potential decrease from Equation 1, i.e.:

    \delta PV = -RT \ln(1-x_2)\qquad (2)

    Where δP is the osmotic pressure and V is the molar volume of the solvent.

    wtf \delta P = RTx_2/V \qquad (3)

    Reverse osmosis

    Main article: Reverse osmosis

    Forward osmosis

    Main article: Forward osmosis

    Osmosis may be used directly to achieve separation of water from a "feed" solution containing unwanted solutes. A "draw" solution of higher osmotic pressure than the feed solution is used to induce a net flow of water through a semi-permeable membrane, such that the feed solution becomes concentrated as the draw solution becomes dilute. The diluted draw solution may then be used directly (as with an ingestible solute like glucose), or sent to a secondary separation process for the removal of the draw solute. This secondary separation can be more efficient than a reverse osmosis process would be alone, depending on the draw solute used and the feedwater treated. Forward osmosis is an area of ongoing research, focusing on applications in desalination, water purification, water treatment, food processing, etc.

    See also

    Wikibooks
    Wikibooks' [[wikibooks:|]] has more about this subject:

    References

    1. ^ Osmosis
    2. ^ http://www.cbse.nic.in

    External links


     
    Translations: Translations for: Osmosis

    Dansk (Danish)
    n. - osmose

    Nederlands (Dutch)
    osmose

    Français (French)
    n. - (Biol, Chim, fig) osmose

    Deutsch (German)
    n. - Osmose

    Ελληνική (Greek)
    n. - (φυσ.) όσμωση

    Italiano (Italian)
    osmosi

    Português (Portuguese)
    n. - osmose (f)

    Русский (Russian)
    осмос

    Español (Spanish)
    n. - ósmosis

    Svenska (Swedish)
    n. - osmos

    中文(简体) (Chinese (Simplified))
    渗透作用, 渗透性

    中文(繁體) (Chinese (Traditional))
    n. - 滲透作用, 滲透性

    한국어 (Korean)
    n. - 삼투

    日本語 (Japanese)
    n. - 浸透

    العربيه (Arabic)
    ‏(الاسم) الأسموزيه ( التناضح)‏

    עברית (Hebrew)
    n. - ‮פעפוע, אוסמוזה, מעבר של חומר מסיס דרך מחיצה לתוך תמיסה סמיכה יותר‬


     
     

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