Right-click on the cell you want to format and click the Format Cells option.
Ctrl - 1 opens the Format Cells dialog box.
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Ctrl - 1 - A will open the Alignment Tab in the Format Cells dialog box.
The Format Cells dialog box.
You can click on the little arrow in the bottom right of any of the groups on the ribbon to open the appropriate tab of the Format Cells dialog box. On the keyboard Ctrl - 1 will open the Format cells dialog box.
CTRL+1
ways to open a display dialog box
Saving a file will not display the dialog box.
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It is on the Alignment tab.
left, right, or center
The "Alignment" tab