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freeze both of the waters and them put them in the barrel. you could still tell them apart since they will be frozen. freeze the water from both jugs and put them in the barrell you could mix the water with (different) coloured jello and lots of sugar so that they harden into two non-mixing lumps in the barral. And not only have you solved the riddle but have a yummy snack afterwards.

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Q: If you have 2 plastic jugs filled with water How can you put all the water into a barrel without using the jugs or any dividers and still tell which water came from which jug?
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