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If you connect the four batteries in series, you get 1.5 x 4 = 6 volts total. So the four batteries give more volts.

If the question is which alternative will deliver more power as in watts, that depends on both the batteries and the application. As an example, a 12 V car battery has higher capacity and can deliver far more watts than eight torch batteries in series for the same number of volts.

But as long as the maximum current the application draws is no higher than what the smallest batteries can deliver, the power (watts) will depend only on voltage.

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Q: What has more power 4 batteries of 1.5 volts each or a single battlery of 4.8 volts?
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