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Alkenes, or hydrocarbons with at least one double bond undergo an addition reaction when combined with bromine (Br2). The general reaction is H2C=CH2 --> H2BrC--CBrH2, and it occurs readily. This reaction is a good way to identify alkenes because bromine has a reddish color, while alkanes and alkenes are colorless. So if bromine is added to an unknown hydrocarbon, the disappearance of the color is an indication of the presence of a pi bond.
Alkenes
The difference between an alkane and an alkene is that: Alkanes have only single bonds between carbon atoms and are said to be saturated: when put in bromine water, the bromine water stays orange - formula: CnH2n+2; Alkenes: have one or more double bond(s) between carbon atoms and are unsaturated: when put in bromine water, the bromine water turns clear - formula: CnH2n.
Bromine dissapear in this reaction !
Use bromine water (Br2) or acidified permanganate (H+/MnO4-) With permanganate: add the permanganate to the alkane and no reaction will occur, add the permanganate to the alkene and you will form a diol the solution will also turn from purple to colourless. With bromine water: add the bromine water to the alkane (plus you need sunlight) and you get a substitution reaction, this is a slow reaction. Add the bromine water to the alkene and you get an immediate addition reaction (this one does not need sunlight). When bromine water reacts with an alkene it is decolourised, the reddish brown bromine water turns from brown to colourless. This is because alkenes are unsaturated and contain a carbon to carbon double bond. If you did the bromine water test in a dark place say a cupboard then the alkene would decolourise but the alkane wouldn't because it needs UV/sunlight in order to react. in practice the cupboard is not necessary as the speed of decolourisation is so much faster with the alkene.
an addition reaction takes place when butene decoulourises bromine solution x
CCL4 is a carrier for Bromine reaction.
Alkenes, or hydrocarbons with at least one double bond undergo an addition reaction when combined with bromine (Br2). The general reaction is H2C=CH2 --> H2BrC--CBrH2, and it occurs readily. This reaction is a good way to identify alkenes because bromine has a reddish color, while alkanes and alkenes are colorless. So if bromine is added to an unknown hydrocarbon, the disappearance of the color is an indication of the presence of a pi bond.
saturated decolourises alkyl kmno4 but unsaturated does not. due to substituition reaction by saturated solution
No, bromine will only add to alkenes, so NO addition reaction to alkanes. Subtitution on alkanes is not possible at standard conditions
Bromine water can test the difference between alkanes and alkenes because the bromine water turns colourless for the alkenes but doesnt change for the alkanes.
bromine water is oxidising in nature. it removes the double bonds and attaches itself to the alkene.
i think the unsaturated fat decolourises it :/
Alkenes
Unsaturated hydrocarbons such as alkenes and alkynes will decolourize bromine water.
Bromine attacks triolein at three places where double bonds exist in the structure, causing saturated molecule. The equation for the reaction of triolein with bromine is C57 H104 06 + 3 Br2 --> C57 H104 06 Br6.
Benzene will not decolourise bromine water as it does not undergo addition reaction. It is highly saturated due to presence electron cloud above and below it.