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Why sulphur have higher negative electron affinity than oxygen?
Wiki User
∙ 11y ago
Due to small size and high electron density of oxygen
compared to sulphur, interelectronic repulsion is higher in oxygen, resulting in less energy being released when an electron is added to oxygen, due to lesser stability after electron is added, which is due to the interelectronic repulsion in the small oxygen atom. Hence electron affinity value is lower. It is an abnormality and exception to the general periodic trend of electronic affinity values.
Wiki User
∙ 11y ago
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What are the trends and exceptions to the trends in electron affinity?
Down the group electron affinity decreases Across a period electron affinity increases. However, it should be noted that chlorine is having higher electron affinity than flourine due to the small size of fluorine atom)
What elements has the largest electron affinity?
AnswerElectron affinity is the energy released when we add an electron to the outermost orbit of the atom. Halogens are the higher in electron affinity, and chlorine has the higher electron affinity than rest of the halogens. The irregularity in the electron affinity trend between Cl and F is due to the small size of the F atom. Although F definitely has a higher attraction for an electron than Cl (as evidenced by its high electro negativity value), the small size of the F atom means that adding an electron creates significant repulsion. Since electron affinity is an energy measurement, the total energy associated with electron affinity winds up being the energy that is released by the electron binding to the nucleus, minus the energy involved in overcoming the electrical repulsion in the outer shell.This makes the fluoride anion so formed unstable due to a very high charge/mass ratio. Also, fluorine has no d electrons which limits its atomic size. As a result, fluorine has an electron affinity less than that of chlorine.
Why doesone atom have a partial negative charge in a polar covalent bond?
Because this atom has a high electronegativity ( affinity for electrons ) and is bonded to an atom with much lower electronegativity. So the electron(s) of the lower electronegative atom spends more time in the orbital of the higher electronegative atom thus giving that end of the molecule a slight negative charge.
What makes a better conductor copper or iron?
Copper is better conductor than iron because copper has higher electron affinity of 1.22948 eV than iron which is 0.16299 eV.
What would happen if there were extra electrons in an atom?
when electron jump from lower energy level to high energy level
Which has higher electron affinity Iodine or bromine?
Bromine has a higher electron affinity.
Who has higher electron affinity between bromine and Iodine?
According to Zumdahl, Group 7A elements (halogens) follow the expected behavior or periodicity as you follow top to bottom. The numbers (top to bottom) are getting closer to 0, so they are decreasing in electron affinity. Bromine has a higher negative # therefore it is a higher electron affinity.---papajohn
Which has higher electron affinity fluorine or chlorine?
Fluorine has higher electron affinity than any other element.
What are the trends and exceptions to the trends in electron affinity?
Down the group electron affinity decreases Across a period electron affinity increases. However, it should be noted that chlorine is having higher electron affinity than flourine due to the small size of fluorine atom)
Do Nonmetals with lower electron affinity have higher reactivity?
No. The most reactive non metal, fluorine, has the highest electron affinity.
Definition of electron affinity?
The energy change that occurs when an electron is added to a neutral atom. This is usually exothermic. Noble Gases are excluded from this. Equation: X(element)+e-(electron)---------> X-1+ energy
Why electron affinity is negative?
It is NOT negative (for the first IE). Because Be's configuration is 1s2 2s2, we observe that it has no vacant orbital to accommodate an electron, meaning that to insert an electron, it has to go into a new sub-orbital, the higher-energy 2p. Hence, you need energy to promote this electron to a 2p level to force Be to accept it.
What is beryllium's electron affinity?
It is NOT negative (for the first IE). Because Be's configuration is 1s2 2s2, we observe that it has no vacant orbital to accommodate an electron, meaning that to insert an electron, it has to go into a new sub-orbital, the higher-energy 2p. Hence, you need energy to promote this electron to a 2p level to force Be to accept it.
What elements has the largest electron affinity?
AnswerElectron affinity is the energy released when we add an electron to the outermost orbit of the atom. Halogens are the higher in electron affinity, and chlorine has the higher electron affinity than rest of the halogens. The irregularity in the electron affinity trend between Cl and F is due to the small size of the F atom. Although F definitely has a higher attraction for an electron than Cl (as evidenced by its high electro negativity value), the small size of the F atom means that adding an electron creates significant repulsion. Since electron affinity is an energy measurement, the total energy associated with electron affinity winds up being the energy that is released by the electron binding to the nucleus, minus the energy involved in overcoming the electrical repulsion in the outer shell.This makes the fluoride anion so formed unstable due to a very high charge/mass ratio. Also, fluorine has no d electrons which limits its atomic size. As a result, fluorine has an electron affinity less than that of chlorine.
Does copper or gold have a higher electron affinity?
Gold; gold has the highest electronic affinity of any atom other than the halogens, due to relativistic effects.
How does electron affinity change as you go from family 1 to 18?
Generally it gets higher/stronger but there are exceptions.
Why is the electron affinity for clorine is greater than the electron affinity for iodine?
Generally electron affinity goes up as you go from left to right across the periodic table, and decreases as you go down a column. However, fluorine is an exception -- and the element with the highest electron affinity is chlorine.(Note that the most electronegative element is fluorine however; 'electronegativity' is not exactly the same as 'electron affinity'.)Electronegativity is the ability of an atom in a molecule to draw bonding electrons to itselfElectron affinity is a measure of the energy change when an electron is added to a neutral atom to form a negative ion.The reason that the electron affinity is not as high as might otherwise be predicted for fluorine, is that it is an extremely small atom, and so it's electron density is very high. Adding an additional electron is therefore not quite as favorable as for an element like chlorine where the electron density is slightly lower (due to electron-electron repulsion between the added electron and the other electrons in the electron cloud).
