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Most compounds are given as their concentration in blood plasma as well as with the conditions of collection. It is a form of standardization used in order to compare results across laboratories and over time. As blood volume and percent hematocrit (a measure of red blood cells) are fairly constant relative to body mass using the concentration in plasma ensures consistency in measurement. Another factor is that red blood cells are not equilibrated with the concentration of all compounds outside the cell equally. Transportation of compounds across the cell membrane is regulated.

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Q: Why use plasma concentration rather than blood concentration in monitoring drug concentration in the body?
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