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Effect of acid and heat on sugar

Sucrose (table sugar) is a disaccharide, meaning it is two simple sugars, glucose and fructose, that have reacted in such a way that they join together, losing a molecule of water in the process. A reaction that produces water is called a condensation reaction. The fructose acts like an acid, and donates a proton. The glucose acts like a base, and donates a hydroxide ion. The proton and the hydroxide ion combine to form water, and the two simple sugars combine to form sucrose.

The reverse reaction, called hydrolysis, is where a water molecule is added to a molecule to break it into two parts. Hydrolysis of sucrose in water happens very slowly all by itself. But if an acid is added, it acts like a catalyst, promoting a faster reaction, but not getting used up in the process. Heating up the solution makes the reaction go even faster.

The result of heating sucrose in water with a little lemon juice or vinegar in it is that much of the sucrose is converted into the two simple monosaccharides. Since fructose is a lot sweeter than sucrose, the result is a sweeter solution, even though glucose is not quite as sweet as sucrose. Since the acid is not used up, the solution is also a little tart, but that can be fixed by adding a weak base like egg whites or baking soda. If there are proteins in the solution, they can also react with the acid to neutralize it.

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Q: Will boiling sugar turn it from mainly sucrose to dextrose?
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Which are types of sugar dextrose fructose sucrose or lactotes?

Dextrose, fructose, and sucrose are the types of sugar. The fourth one is glucose.


What is the name for sugar?

dextrose, sucrose, or glucose


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What is the difference between ordinary granulated sugar and brewing sugar?

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What is the difference between granulated sugar and brewing sugar?

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Can you use dextrose in layer cake?

Dextrose is much sweeter than Sucrose, and is a great subsitute for sucrose when you are looking to reduce the sugar content or reduce the volume that sugar is taking up in a baked good. I've read estimates that dextrose 10-16 times sweeter than regular sugar, but I don't have exact numbers. The best thing to do is taste your batter while you're adding the dextrose. I have made cookies, muffins and brownies with dextrose and they turned out well. Given my experience, I think it would work with cake as well. If the taste it too noticably different than just using sucrose, try adding some sucrose or fructose in addition to the dextrose. Hope this helps. Dextrose is only 70-80% as sweet as sugar. The preceding answer is incorrect. I don't think you can easily substitute. Will definitely require some experimentation.