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The simple answer is it does! There are compounds aluminum dialkyls that contain an aluminum-aluminum bond. (quoted in Cotton and Wilkinson 6th edition) There are not many examples known- metal metal bonding is more common with gallium and indium. Gallium forms gallium- gallium bonds in the Ga2I62- anion and in some complexes. Indium also forms indium-indium bonds in for example the In2Br62- anion and recently a compound with a short chain of indium atoms was discovered. A detailed explanation of why the aluminum is different is complex and is due to a number of factors:

  • the strength of the bond
  • the thermodynamic stability of the comound in realtion to the decomposition products
  • the "kinetic" stability of the compound e.g. how easily is it "attacked" by other molecules.
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12y ago
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12y ago

A number of theories have been developed to explain this. The one that provides the best explanation for observations is called the free electron theory. According to this theory, all of the valence electrons in a metal are available and shared by all of the atoms. This differs from sharing of electrons between individual atoms (covalent bonding), which cannot explain the behavior of metals.

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Q: Why is it not possible for aluminum atoms to form covalent bonds with other aluminum atoms?
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