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Does the amount of potassium iodide added to the potassium iodate solution affect the amounts of iodine liberated in iodometric titration?
Yes, the amount of potassium iodide added to the potassium iodate solution in iodometric titration affects the amount of iodine liberated. Potassium iodide serves as a reducing agent, reacting with the iodate ion to form iodine. The quantity of potassium iodide added determines the rate and completeness of this reaction, impacting the amount of liberated iodine available for titration.
Why potassium thiocyanate is added in redox iodometric titration of copper sulphate?
Cu2I2 is precipitates in light pink colour due to adsorption of I2 and the precipitate releases I2 very slowly. Therefore very small amount of potassium thiocyanate is added towards the end point which helps to displace the adsorbed I2 quickly by combining with Cu2I2 to form CuSCN which has less tendency to adsorb I2.
Why KI is added in redox iodometric titration even in the presence of sodium thiosulfate as a reducing agent?
In iodometric titrations sodium thiosulfate is the titrant whereas the KI will reduce the analyte; eg: Cu2+ to Cu+. The I2 produced is then titrated by the sodium thiosulphate. Cu2+ + I- --> CuI + I3- I3- + 2 S2O32- ¾® 3 I- + S4O62- To answer your question: KI (reducing agent) is added to generate the iodine by the reduction of the analyte (Cu2+) The formed iodine is then back-titrated with thiosulfate (titrant) to determine the amount of analyte originally present. As you can see the KI and sodium thiosulfate serve two different purposes. KI improves solubility of Iodine
Can you have viva questions on titration?
Yes, it is possible to have viva questions on titration. Some potential questions could focus on the principles of titration, the choice of indicators, calculations involved in titration, different types of titrations, sources of errors in titration, and applications of titration in various industries.
IF air oxidation of acid-iodide solution occurs what wiil happen to the iodometric titration?
Long story short, iodine in the solution made earlier through a reducing agent is weakly soluble and prone to loss to the air. Therefore, let's say you are using the titration to determine concentration of the titrant, the concentration would be off from the "true" concentration because you've lost some reactants.
Why is it recommended to carryout iodometric titrations as quick as possible?
Iodometric titrations involve the titration of iodine with a reducing agent. Iodine is volatile and can escape into the air, which can lead to errors in the titration results. To minimize these errors, it is recommended to carry out iodometric titrations as quickly as possible to prevent the loss of iodine and ensure accurate results.
What are iodometric and iodometric titration?
Iodometric titration involves determining the concentration of a substance by measuring the amount of iodine generated in a reaction. Iodometric titration, on the other hand, refers to a type of redox titration that uses iodine as the titrant to determine the amount of a substance, typically an oxidizing agent, present in a sample.
Why you do not use H2SO4 in iodometric titration?
Using H2SO4 in iodometric titration can lead to the formation of H2O2, which interferes with the reaction. It can also oxidize iodide ions prematurely, affecting the accuracy of the titration. Therefore, a different acid like HCl is typically used in iodometric titration.
What is the difference between iodometric titration and iodimetric titration?
Iodometric titration involves the titration of iodine with a reducing agent, while iodimetric titration involves the titration of iodide with an oxidizing agent. In iodometric titration, iodine is detected by a starch indicator to determine the end point, while in iodimetric titration, iodide ion concentration is determined by titration with a standard solution of an oxidizing agent.
Is iodometric titration and redox titration is same?
No, they are not the same, but 1 is part of 2.Iodometric titration is just one of the (larger) group (or class) of oxidimetric titrations, which in turn is part of the much (larger) group (or class) of volumetric analysis method.
Can we carry out an iodometric titration using a potentiometer?
No, iodometric titration is typically done using a standard titration setup with a burette and indicator to detect the endpoint. A potentiometer measures the voltage produced in a system, making it unsuitable for this type of titration.
Why analysis of Cu from brass solution is considered as an iodometric titration?
Copper in brass can be oxidized to Cu2+ by iodine in a redox reaction. The iodine acts as the titrant in the reaction and the copper is being titrated. It is considered an iodometric titration due to the involvement of iodine in the titration process.
Why is the indicator not added to the titration flask at the begging of the iodomettic titration?
Adding the indicator at the beginning of the iodometric titration can react with the iodine present, which can lead to errors in the titration results. By adding the indicator after most of the iodine has reacted, it ensures that the endpoint is more accurate and reliable.
What is the function of potassium iodide in iodometric titration?
Potassium iodide is used in iodometric titration as a source of iodide ions. It reacts with iodine to form triiodide ions, which are then titrated with a standard solution of thiosulfate to determine the concentration of the oxidizing agent.
Why use sodium bicarbonate in iodometric titration?
Sodium bicarbonate is used in iodometric titration to react with excess iodine that may be present after the reaction with the analyte. This helps neutralize the solution and prevent any further reactions that could interfere with the titration endpoint. Additionally, sodium bicarbonate helps stabilize the pH of the solution during the titration process.
What is meant by drift in a KF titration?
Drift in a Karl Fischer titration refers to a gradual change in the baseline of the titration curve over time. This can occur due to factors such as contamination of the reagents, improper sealing of the titration cell, or instability in the titration system. Drift can affect the accuracy of the moisture determination and should be monitored and corrected during the analysis.
Why keep in dark in iodometric titration?
Keeping the solution in the dark during iodometric titration helps prevent any unwanted reactions due to exposure to light, which could interfere with the accuracy of the titration results. Light can induce photoreactions that can alter the chemical species being titrated, leading to incorrect readings. Therefore, maintaining the solution in the dark helps ensure the reliability and precision of the titration.
