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Polysaccharides are essentially many carbon sugar "rings" linked together. They are carbohydrates, and our bodies break them down into monosaccharides (single "rings") to gain energy. To provide energy is their main function. In contrast, a peptide bond is formed between two amino acids via dehydration synthesis. Amino acids are the monomers for proteins within the body, who function in part to catalyze reactions and carry out other directions of DNA. Many peptide bonded amino acids = a polypeptide. The most basic difference would be that polypeptides are proteins, where as polysaccharides are carbohydrates.

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