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To find the mass of iron in CuFeS2, we first calculate the molar mass of CuFeS2: Cu (copper) has a molar mass of 63.5 g/mol, Fe (iron) has a molar mass of 55.8 g/mol, and S (sulfur) has a molar mass of 32 g/mol. Adding these together gives a molar mass of 151.3 g/mol for CuFeS2. Next, calculate the mass percentage of iron in CuFeS2 by dividing the molar mass of iron by the molar mass of CuFeS2 and multiplying by 100. The percentage of iron is approximately 37%, so in 86.6 grams of CuFeS2, the mass of iron would be 0.37 * 86.6 grams = 32 grams.

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