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You feel hungover mainly because alcohol inhibits the antidiuretic hormone (ADH) causing you to urinate more frequently and become dehydrated. Also EtOh is metabolized to acetaldehyde which can form free radicals that sequester anti oxidant vitamins. The aldehyde can remain in tissue longer and is associated with other hang over feelings.

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Q: Why does having a beer when your hungover make you feel better?
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