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According to Organicfacts.net:

Mineral content: If you eat potatoes regularly, you ensure a good supply of water and ions in your body. This is because, potato is rich in potassium.The concentration being higher in the skin and just beneath it. So,eating the potato with its skin is always beneficial. Potato alsocontains calcium, iron, and phosphorus.

I'm not sure it cooking reduces the mineral content greatly. But according to the source above you should not peel the potato if you want to preserve nutritional value. Please note that when potatoes have green skin you should avoid eating that green parts. It has a high concentration of a naturally toxin that may make you sick.

more potato info: http://www.answers.com/what%20is%20the%20nutritional%20value%20of%20potatoes

AnswerPotatoes, whether raw or cooked, are a good source of potassium. Potassium and other electrolytes, along with water, are necessary to prevent dehydration. The amount of potassium one loses during exercise is relatively small compared to a whole potato, and it will be much more important to consume plenty of water. Simply consuming an electrolyte-based liquid such as Gatorade will help to prevent dehydration.
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Q: Are raw potatoes a good source of potassium to help prevent dehydration?
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How potassuim potatoes are prepared?

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