HeyHoward==If it is coolant the engine will overheat quickly and the engine will smoke white smoke. The head gaskets will need replaced. It can be normal condensation if it is pretty clear water. Good luck, Joe
The smoke from your muffler has a smell because what is coming out of the muffler is the products of the incomplete combustion of your fuel. Some of those products are gases and vapors that have color and some are dark but small particles - that is what you call smoke. But some of what comes out are various chemicals that your nose detects as odors.
Replace If it has a hole or leak in it, replace it. A leaking muffler is a very dangerous thing. I know, I had a very serious accident from a leaking muffler. Carbon Monxide is a odorless, tasteless, killer. It put me to sleep and I never saw it coming. I did however wake up just in time to see the tree coming, and was unable to miss it. Spent 2 weeks in the hospital over a $20 muffler. Get yourself a new muffler.
A little water coming from the muffler for the first few minutes after you start the car is normal. Water vapor condenses inside the exhaust system when you stop the motor, and is expelled the next time you start. If there is a lot of water coming out, and it keeps coming even after the car is thoroughly warmed up, then it could be coolant leaking into the cylinders from a bad head gasket or a cracked block. You can have a mechanic do a pressure test on your cooling system to test for this. He also can test for the presence of exhaust gasses in the cooling system.
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