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Because urea and aspirin overall are polar compounds, and their intermolecular forces are stronger than napthalene or dichlorobenzene. This means it takes more kinetic energy (heat) to separate their molecules, which translates as a higher melting and boiling points.

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10y ago
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Q: Why does urea and aspirin have higher melting points than napthalene and pi-dicholorbenzene?
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