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Hydrogen atoms have only one electron, to fill its outer electron shell it needs one more. (This is an exception to the octet rule.) The elements found in the Halogen family have seven electrons in their outer shell and need one more to fill it (these follow the octet rule).

Both Hydrogen and Halogens have similar bonding properties since they all need only one more electron; they can form one single-bond with another atom. If a hydrogen atom is moved then a Halogen is readily able to take its place.

For example: Any alkane compound obtained by replacing every hydrogen atom of a halogen is called a perhaloalkane.

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Q: What are some hydrogen atoms replaced by atoms from the halogen family?
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Some hydrogen atoms replaced by atoms from the halogen family?

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