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5 * 10**-12 mol

32 * 10**-9 mol

Concentration (M) * Volume (L) = mols

C1*V1=C2*V2

(5*10**-12)*V1=(32*10**-9)*V2

(5*10**-12)*V1/(32*10**-9)=V2

(5*10**-3)*V1/32=V2

The volume of the 5 picomolar solution that you wish take = V1

The volume of the 32 nanomolar solution that you need to make V1 at 5pM concentration = V2

Take V2, and place into graduated cylinder and fill to V1.

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