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For this you need the atomic (molecular) mass of NaCl. Take the number of grams and divide it by the Atomic Mass. Multiply by one mole for units to cancel. NaCl=58.5 grams

20.0 grams NaCl / (58.5 grams) =.342 moles NaCl

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Q: How many moles are in 20.0 grams of NaCl?
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