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Spectroscopy

Spectroscopy is a branch of analysis devoted to identifying elements and compounds through the measurement of the absorption, scattering, or emission of electromagnetic radiation by atoms or molecules. It is widely used in physical and analytical chemistry, as well as in astronomy and remote sensing. Questions and answers here have to do with anything that has to do with Spectroscopy.

513 Questions

Why is light so narrow on the spectrum?

Light is narrow on the spectrum because it consists of electromagnetic waves with specific wavelengths. Each color of light corresponds to a different wavelength, resulting in the distinct colors we see in the visible spectrum. This narrow range is due to the specific interactions between photons and atoms/molecules that determine the wavelengths of light that are emitted or absorbed.

What does the suffix spec mean?

The suffix "spec" comes from the Latin word "specere," meaning "to look at" or "to behold." It is often used in words to indicate something related to sight, appearance, or observation. For example, words like inspect, respect, and aspect.

In what material were cells first seen in?

Different atoms, particularly carbon, hydrogen, nitrogen and oxygen, made up molecules into such things as proteins, lipids, phospholipids, enzymes, and amino acids. These molecules are part of what makes up a cell, including DNA, and is obviously the first "material" that was first seen in cells.
Cells are made/constructed of many different chemicals, but when were they first seen? In the 1670's, Anton van Leeuwenhoek saw microscopic organisms with a microscope that he had fashioned... but there could have been someone who saw them before that... certainly people who knew of their existence.

How do planes reduce air resistance?

You can reduce the amount of friction by putting wheels on an object or by taking away all of the grip on the object. You can also make dure the groung is really slippery. You can by adding oil to make it slippery ths is done in most of the machines and gadgets that we use daily.friction will also be reduced if surface is smooth or slippery

What is derivative spectroscopy?

A spectrum that is the result of applying a derivative transform to the data of the original spectrum. Derivatives of spectra are very useful for two reasons:

1. First, and second derivatives may swing with greater amplitude than the primary spectra. For example, a spectrum suddenly changes from a positive slope to a negative slope, such as at the peak of a narrow feature (see the figure below). The more distinguishable derivatives are especially useful for separating out peaks of overlapping bands.

2. In some cases derivative spectra can be a good noise filter since changes in base line have negligible effect on derivatives. For example, scattering increases with wavelength for some biologically active macromolecules causing an increasing slope of the absorbance baseline.

A commonly used approximation of the first derivative is: dα/dλ = [α (λ + Δλ) - α (λ - Δλ)] / 2Δλ.

A more accurate approximation of the first and higher order derivatives is presented in thorough explanations by Whitaker1 and Morrey2. Still other methods involve a best fit match to the curve on the features of interest and performing higher order derivatives with numerical analysis.

Derivative spectra yield good signal-to-noise ratios only if the difference of noise levels at the endpoints of the interval is small enough to yield a noise equivalent Δdα/dλ calculation much smaller than the absorbance.

Enumerate the theories of nature of light?

  1. Wave theory - light is a type of electromagnetic wave proposed by scientists like Maxwell and Huygens.
  2. Particle theory - light consists of particles called photons, advocated by scientists like Einstein and Planck.
  3. Wave-particle duality - the concept that light exhibits both wave-like and particle-like behavior, proposed by quantum mechanics.

What refracts more red or violet?

Violet light refracts more than red light because violet light has a shorter wavelength and higher frequency, causing it to bend more when passing through a medium. This is known as dispersion, where different colors of light are separated due to their different wavelengths.

Use of kbr in ir spectroscopy?

Potassium bromide (KBr) is commonly used in infrared (IR) spectroscopy as a method to prepare solid samples for analysis. The sample is mixed with KBr and compressed into a pellet, which allows for better handling and analysis. KBr has a wide transmission range in the IR spectrum and is transparent to infrared radiation, making it a suitable medium for the sample to be measured.

What a spectrograph looks like?

A spectrograph typically consists of a long, narrow slit to allow light in, a diffraction grating or prism to disperse the light into its component wavelengths, and a detector to capture and record the resulting spectrum. The final output is a graph or image showing the intensity of light at different wavelengths.

What is dipole moment of solvents?

The dipole moment of a solvent is a measure of its polarity, which indicates the separation of positive and negative charges within the molecule. Highly polar solvents have a large dipole moment, while nonpolar solvents have a dipole moment close to zero. The dipole moment of a solvent influences its ability to dissolve polar or ionic solutes.

What is the infrared spectra of polyacrylonitrile?

The infrared spectrum of polyacrylonitrile typically shows absorption peaks associated with C-H stretching vibrations, C≡N stretching vibrations, and N-H bending vibrations. The exact peaks and intensities can vary depending on the molecular structure of the polymer and any additional functional groups present.

Can you do project in inoganic using Ftir?

Yes, an FTIR (Fourier-transform infrared spectroscopy) can be used in an inorganic project for analyzing various compounds, identifying functional groups, and characterizing materials based on their infrared spectra. This technique is particularly useful for studying inorganic compounds due to its sensitivity to metal-ligand vibrations and can provide valuable information on the composition and structure of the samples.

What is electromagnetic spectrum diffusion?

Electromagnetic spectrum diffusion refers to the spreading out of electromagnetic waves as they travel through a medium. This can occur due to factors such as interference, scattering, or reflections off surfaces. Diffusion can lead to a decrease in signal strength or quality in communication systems.

Why are the white clothes dipped in blue after the wash?

Dipping white clothes in a blue dye solution after wash, often referred to as bluing, is traditionally done to counteract yellowing or dinginess that may occur in white fabrics over time. The blue tint helps to enhance the appearance of whiteness by neutralizing the yellow tones, making the clothes appear brighter and cleaner.

Why does the light of a bulb seem to be fading when sunlight is coming through window?

What is being observed in a situation where a light bulb seems less bright when the sun is shining through a window is based on the way the eye works. Let's take a moment and look at the issues.

When a light bulb is on, we see the light and our brain "assigns" a "brightness" to the lamp. If it's a bright, sunny day and the lamp is near a window, all bets are off. The voltage to the lamp is the same, and the lamp is still emitting all the light (photomic energy) that it has been. But the "extra" light from the sun that streams through the window will "overload" the eye to a certain extent. The light will not seem as bright, and it is all because of the way the eye works. It has nothing to do with the lamp.

Calculate the doublet separation 3p orbital of sodium atom?

The doublet separation of a 3p orbital in a sodium atom refers to the energy difference between the two degenerate (same energy) p orbitals. In the case of the 3p orbital in sodium, the doublet separation is determined by the spin-orbit coupling effect and is approximately 0.002 electron volts.

Is n-pentane polar or nonpolar?

n-Pentane is considered nonpolar because it contains only carbon and hydrogen atoms bonded together with nonpolar covalent bonds. The symmetrical arrangement of these atoms results in a molecule with no overall dipole moment.

What are the disadvanatges of mass spectroscopy?

Some disadvantages of mass spectrometry include the need for expensive equipment and skilled operators, as well as the requirement for sample preparation which can be time-consuming. Additionally, interpretation of mass spectra can sometimes be complex and may require expertise in the field.

Did Anybody know about deltapsi2 software using ellipsometry?

Deltapsi2 is a very hard program to use. I have used about every type of software out there and would recommend WVASE32 or CompleteEASE. Both of these are very easy to use and have models that you can build complicated anisotropic structures as well as semi-absorbing and absorbing materials.

I am using on a ellipsometer developed in the laboratory where I am working. I have written some basic software to perform analysis, but you explain that its exists a very powerful software named "CompleteEase"

I would like to know, if it is possible to get it but I doubt a little bit because it is developped by a private company WOOLLAM as I have seen on the net.

Could you give me some advise about this software.

Thanks a lot

How do you compare the prism and grating spectrum?

Grating spectra is made of a series of step like material where the beam of light hits either the short face (echelle) or the long face (echellette) which disperses the beam into separate wavelengths. Prisms can be made in different ways but they theory is based on refractive index. The beam passes through the prism and the wavelengths disperse, where dispersion increases with shorter wavelength.

Parameter which boarding the spectral line?

The parameter governing the width of a spectral line is known as the linewidth. This can be influenced by various factors such as the natural broadening due to the uncertainty principle, Doppler broadening from thermal motion of particles, and pressure broadening from collisions with neighboring atoms or molecules. The linewidth provides information about the physical conditions of the emitting source, such as temperature, density, and pressure.

How works piezoelectric infrared radiation detector of triglycline sulfate?

Piezoelectric infrared radiation detectors made of triglycine sulfate can convert infrared radiation into detectable electrical signals. When infrared radiation hits the crystal structure of the triglycine sulfate, it creates an electric charge due to the piezoelectric effect, which can then be measured as a voltage signal. This allows the detector to sense and quantify the presence of infrared radiation.

Which ray does not belong in the electromagnetic spectrum?

Sound waves do not belong in the electromagnetic spectrum. Sound waves are mechanical waves that require a medium (such as air or water) to travel through, unlike the electromagnetic waves that can travel through a vacuum.

In what portion of the electromagnetic spectrum does the sun emit most energy?

The sun's radiation comes as 45 percent visible light. 40 percent infared, and the remainder as Ultraviolet.

This is why the Sun is damaging to our eyes as well as skin while giving us the light we need.